Add-on air pollution control device (APCD) means
equipment installed in the ventilation system of chromium electroplating
and anodizing tanks for the purposes of collecting and containing
chromium emissions from the tank(s).
Administrator means the Administrator of the United
States Environmental Protection Agency or his or her authorized
representative (e.g., a State that has been delegated the
authority to implement the provisions of 40 CFR part 63).
Air pollution control technique means any method,
such as an add-on air pollution control device or a chemical fume
suppressant, that is used to reduce chromium emissions from chromium
electroplating and chromium anodizing tanks.
Area source means any stationary source of hazardous
air pollutants that is not a major source as defined below in
this appendix. Another term for area source is "nonmajor
source."
Base metal means the metal or metal alloy that comprises
the workpiece.
Bath component means the trade or brand name of
each component(s) in trivalent chromium plating baths. For trivalent
chromium baths, the bath composition is proprietary in most cases.
Therefore, the trade or brand name for each component(s) can
be used; however, the chemical name of the wetting agent contained
in that component must be identified.
Chromic acid means the common name for chromium
anhydride (CrO3).
Chromium anodizing or chromic acid anodizing means
the electrolytic process by which an oxide layer is produced on
the surface of a base metal for functional purposes (e.g., corrosion
resistance or electrical insulation) using a chromic acid solution.
In chromium anodizing, the part to be anodized acts as the
anode in the electrical circuit, and the chromic acid solution,
with a concentration typically ranging from 50 to 100 grams
per liter (g/L), serves as the electrolyte.
Chromium electroplating or chromium anodizing tank
means the receptacle or container in which hard or decorative
chromium electroplating or chromium anodizing occurs.
Composite meshpad (CMP) system means an add-on
air pollution control device typically consisting of several meshpad
stages. The purpose of the first stage is to remove large particles.
Smaller particles are removed in the second stage, which consists
of the composite mesh pad. A final stage may remove any reentrained
particles not collected by the composite mesh pad.
Decorative chromium electroplating means the process
by which a thin layer of chromium (typically 0.003 to 2.5 microns)
is electrodeposited on a base metal, plastic, or undercoating
to provide a bright surface with wear and tarnish resistance.
In this process, the part(s) serves as the cathode in the electrolytic
cell and the solution serves as the electrolyte. Typical current
density applied during this process ranges from 50 to 220 Amperes
per square feet (A/ft2) for total plating times ranging
between 0.5 to 5 minutes.
Electroplating or anodizing bath means the electrolytic
solution used as the conducting medium in which the flow of current
is accompanied by movement of metal ions for the purposes of electroplating
metal out of the solution onto a workpiece or for oxidizing the
base material.
Emission limitation means, for the purposes of this
regulation, the concentration of total chromium allowed to be
emitted expressed in milligrams per dry standard cubic meter (mg/dscm),
or the allowable surface tension expressed in dynes per centimeter
(dynes/cm).
Facility means the major or area source at which
chromium electroplating or chromium anodizing is performed.
Fiber-bed mist eliminator (FBME) means an add-on air pollution control device that removes contaminants from a gas stream through the mechanisms of inertial impaction and Brownian diffusion. These devices are typically installed downstream of another control device, which serves to prevent plugging, and consist of one or more fiber beds. Each bed consists of a hollow cylinder formed from two concentric screens; the fiber between the screens may be fabricated from glass, ceramic plastic, or metal.
Foam blanket means the type of chemical fume suppressant
that generates a layer of foam across the surface of a solution
when current is applied to that solution.
Fresh water means water, such as tap water, that
has not been previously used in a process operation or, if the
water has been recycled from a process operation, it has been
treated and meets the effluent guidelines for chromium wastewater.
Fume suppressant (FS) means any chemical agent that
reduces or suppresses fumes or mists at the surface of an electroplating
or anodizing bath; other terms for fume suppressant are chemical
fume suppressant and mist suppressant.
Hard chromium electroplating or industrial chromium
electroplating means a process by which a thick layer of chromium
(typically 1.3 to 760 microns) is electrodeposited on a base material
to provide a surface with functional properties such as wear resistance,
a low coefficient of friction, hardness, and corrosion resistance.
In this process, the part serves as the cathode in the electrolytic
cell and the solution serves as the electrolyte. Hard chromium
electroplating process is performed at current densities typically
ranging from 150 to 600 A/ft2 for total plating
times ranging from 20 minutes to 36 hours depending
upon the desired plate thickness.
Hexavalent chromium means the form of chromium in
a valence state of +6.
Large, hard chromium electroplating facility means
a facility that performs hard chromium electroplating and has
a maximum cumulative potential rectifier capacity greater than
or equal to 60 million amperehours per year (amphr/yr).
Major source means any stationary source or group
of stationary sources located within a contiguous area and under
common control that emits or has the potential to emit considering
controls in the aggregate, 10 tons per year or more of any
hazardous air pollutant, or 25 tons per year or more of any
combination of hazardous air pollutants.
Maximum cumulative potential rectifier capacity
means the summation of the total installed rectifier capacity
associated with the hard chromium electroplating tanks at a facility,
expressed in amperes, multiplied by the maximum potential operating
schedule of 8,400 hours per year and 0.7, which assumes that
electrodes are energized 70 percent of the total operating
time. The maximum potential operating schedule is based on operating
24 hours per day, 7 days per week, 50 weeks per
year.
Operating parameter value means a minimum or maximum
value established for a control device or process parameter which,
if achieved by itself or in combination with one or more other
operating parameter values, determines that an owner or operator
is in continual compliance with the applicable emission limitation
or standard.
Packed-bed scrubber (PBS) means an add-on air pollution
control device consisting of a single or double packed bed that
contains packing media on which the chromic acid droplets impinge.
The packed-bed section of the scrubber is followed by a mist
eliminator to remove any water entrained from the packed-bed section.
Research or laboratory operation means an operation
whose primary purpose is for research and development of new processes
and products, that is conducted under the close supervision of
technically trained personnel, and that is not involved in the
manufacture of products for commercial sale in commerce, except
in a de minimis manner.
Small, hard chromium electroplating facility means
a facility that performs hard chromium electroplating and has
a maximum cumulative potential rectifier capacity less than 60 million
amphr/yr.
Stalagmometer means a device used to measure the
surface tension of a solution.
Surface tension means the property, due to molecular
forces, that exists in the surface film of all liquids and tends
to prevent liquid from spreading (expressed in dynes/cm).
Tank operation means the time in which current and/or
voltage is being applied to a chromium electroplating tank or
a chromium anodizing tank.
Technology Transfer Network (TTN) means a network
of electronic bulletin boards developed and operated by EPAs
Office of Air Quality Planning and Standards. The network provides
information and technology exchange in different areas of air
pollution control, ranging from emission test methods to regulatory
air pollution models. The service is free, except for the cost
of the phone call. The TTN may be accessed from a computer through
the use of a modem and communications software.
Tensiometer means a device used to measure the surface
tension of a solution.
Trivalent chromium means the form of chromium in
a valence state of +3.
Trivalent chromium process means the process used
for electrodeposition of a thin layer of chromium onto a base
material using a trivalent chromium solution instead of a chromic
acid solution.
Wetting agent means the type of chemical fume suppressant that reduces the surface tension of a liquid.